Open-Framework Manganese(II) and Cobalt(II) Borophosphates with Helical Chains: Structures, Magnetic, and Luminescent Properties.
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DOI: 10.1021/acs.inorgchem.7b01423
Abstract: Two borophosphates, (NH4)1-2xM1+x(H2O)2(BP2O8)·yH2O with M = Mn (I) and Co (II), synthesized hydrothermally crystallize in enantiomorphous space groups P6522 and P6122 with a = 9.6559(3) and 9.501(3) Å, c = 15.7939(6) and 15.582(4) Å, and… read more here.
Keywords: open framework; helical chains; framework manganese; mn2 co2 ... See more keywords