Photoluminescence and Magnetism Study of Blue Light Emitting the Oxygen-Bridged Open-Cubane Cobalt(II) Cluster
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DOI: 10.1007/s10876-018-1406-2
Abstract: A new cubane-based cobalt(II) cluster, [Co4L4] (1), where H2L = 2-((E)-(2-hydroxyethylimino) methyl)-4-chlorophenol has been prepared using a solvothermal process and characterized by structural, optical and magnetism. The crystal structure of 1 consists of a tetranuclear Co4O4 core… read more here.
Keywords: magnetism; cobalt; cubane; cobalt cluster ... See more keywords
Cage-like crystal packing through metallocavitands within a cobalt cluster-based supramolecular assembly.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt00747k
Abstract: A cobalt (Co) supramolecular triple-stranded helicate, [Co8(PDA)6(Br-PTA)3(DMF)4(H2O)2] (1) (PDA = 2,6-pyridinedicarboxylate, Br-PTA = 5-bromoisophthalate, DMF = dimethylformamide), is successfully synthesized and fully characterized. The solid-state structure of 1 shows that four cobalt atoms are coordinated… read more here.
Keywords: cobalt; crystal packing; cage like; geometry ... See more keywords