Magnetic moments of small cobalt clusters revisited: The contribution of 3d and 4s electrons
Sign Up to like & getrecommendations! Published in 2019 at "International Journal of Mass Spectrometry"
DOI: 10.1016/j.ijms.2019.01.004
Abstract: Abstract The magnetic moment of small cobalt clusters shows large variations with the cluster size, both theoretically and experimentally. In this work we present results from density functional calculations using both the hybrid B3-LYP as… read more here.
Keywords: cobalt; magnetic moments; moments small; spin magnetic ... See more keywords
Synthesis of boron imidazolate frameworks with cobalt clusters for efficient visible-light driven CO2 reduction
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry A"
DOI: 10.1039/c9ta04842a
Abstract: A porous crystalline boron imidazolate framework, with a high density of trinuclear cobalt clusters, exhibits efficient photocatalytic performance for CO2 reduction with a CO evolution rate of 5830 μmol g−1 h−1 under visible-light irradiation. read more here.
Keywords: cobalt clusters; co2 reduction; visible light; boron imidazolate ... See more keywords
Supramolecular isomorphic dodecanuclear cobalt clusters with the same metal shell but different core ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00915c
Abstract: In this work, we report two supramolecular isomorphic dodecanuclear cobalt complexes, [Co12(mtz)3(L)6(NO3)2(OH)(N3)3]·(OH)3 (1) and [Co12(mtz)3(L)6(NO3)2(OH)(N3)(OAc)]·(OH)4 (2), (Hmtz = 5-methyl-1H-tetrazole, H2L = 7,7'-(ethane-1,1-diyl) diquinolin-8-ol) crystallizing in the P̄ space group with the same unit cell parameters.… read more here.
Keywords: dodecanuclear cobalt; isomorphic dodecanuclear; metal shell; supramolecular isomorphic ... See more keywords