Bridging and axial carbene binding modes in cobalt corrole complexes: effect on carbene transfer.
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DOI: 10.1039/d0cc07073d
Abstract: Catalytically relevant intermediates in carbene transfer reactions from a diazo precursor were investigated using cobalt corrole complexes. Two divergent mechanisms are proposed depending on the oxidation state of the cobalt center. Mechanistically driven factors for… read more here.
Keywords: cobalt corrole; carbene transfer; carbene; corrole complexes ... See more keywords