Synthesis and biological evaluation of salophen nickel(II) and cobalt(III) complexes as potential anticancer compounds
Sign Up to like & getrecommendations! Published in 2023 at "Archiv der Pharmazie"
DOI: 10.1002/ardp.202200655
Abstract: Recent in vitro investigations of N,N′‐bis(salicylidene)‐1,2‐phenylenediamine (SAP) iron(III) complexes substituted with alkyl (ethyl, propyl, butyl) carboxylates at position 4 in tumor and leukemia cells revealed strong cytotoxic activity. In continuation of this study, analogous nickel(II)… read more here.
Keywords: iii; nickel cobalt; iii complexes; cobalt iii ... See more keywords
Functional Disruption of Gli1‐DNA Recognition via a Cobalt(III) Complex
Sign Up to like & getrecommendations! Published in 2022 at "ChemMedChem"
DOI: 10.1002/cmdc.202200025
Abstract: The aberrant activation of the Gli family of zinc finger transcription factors (ZFTFs) is associated with several types of human cancer, including medulloblastoma and basal cell carcinoma. We have reported the use of cobalt(III) Schiff‐base… read more here.
Keywords: dna; cobalt iii; gli1; dna recognition ... See more keywords
Graphene-Supported Cobalt(III) Complex of a Tetraamidomacrocyclic Ligand for Oxygen Reduction Reaction
Sign Up to like & getrecommendations! Published in 2017 at "Catalysis Letters"
DOI: 10.1007/s10562-017-2243-x
Abstract: AbstractPolymer electrolyte membrane fuel cells (PEMFCs) are at the cusp of providing large scale energy solutions, yet challenges in developing high performance, durable, and cost effective platinum catalyst alternatives continue to impede commercialization efforts. A… read more here.
Keywords: graphene; graphene supported; supported cobalt; cobalt iii ... See more keywords
Phenoxazinone synthase and antimicrobial activity by a bis(1,3-diamino-2-propanolate) cobalt(III) complex
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Chemical Sciences"
DOI: 10.1007/s12039-018-1562-9
Abstract: In this work, we have synthesised and structurally characterized a mononuclear cobalt(III) complex, $$[\hbox {Co(2-O-pn)}_{2}]\hbox {Cl}^{.} \hbox {2H}_{2} \hbox {O}$$[Co(2-O-pn)2]Cl.2H2O (1), (2-O-pn = 1,3-diamino-2-propanolate). From the X-ray structure of the cobalt complex, it is revealed… read more here.
Keywords: cobalt iii; hbox hbox; cobalt; iii complex ... See more keywords
Dehydration of primary amides to nitriles catalyzed by [CNC]-pincer hydrido cobalt(III) complexes
Sign Up to like & getrecommendations! Published in 2019 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2018.12.002
Abstract: Abstract The dehydration reactions from primary amides to nitriles were catalyzed by the [CNC]-pincer hydrido cobalt(III) complexes [(ortho-F4C6 CH N C10H6)Co(III)(H)(PMe3)2] (1), [(2,5-F2C6H2 CH N C10H6)Co(III)(H)(PMe3)2] (2) and [(2,4,5-F3C6H CH N C10H6)Co(III)(H)(PMe3)2] (3) as catalysts… read more here.
Keywords: iii; amides nitriles; hydrido cobalt; cobalt iii ... See more keywords
Trinuclear and polymeric cobalt(II or II/III) complexes with an arylhydrazone of acetoacetanilide and their application in cyanosilylation of aldehydes
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.07.004
Abstract: Abstract The new trinuclear [Co II (H 2 O) 2 (Me 2 NCHO) 2 {Co III (1κ NOO′ :2κ O″ -μ-HL)} 2 (1κ NOO′ )]·2H 2 O ( 1 ) and polymeric [Co II (1κ… read more here.
Keywords: iii; polymeric cobalt; trinuclear polymeric; complexes arylhydrazone ... See more keywords
Tuning the redox potentials of ternary cobalt(III) complexes containing various hydroxamates
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.07.026
Abstract: Abstract Sixteen cobalt(III) complexes incorporating one of the investigated 4N donor tripodal amines in the presence or absence of differently substituted hydroxamates have been synthesized and the effect of the nature of the N-donor, size… read more here.
Keywords: iii; cobalt; iii complexes; bha ... See more keywords
Nickel(II) and Cobalt(III) bis(dioxolene) complexes with di(2-pyridyl)imine ligands: Synthesis and magnetic properties
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119869
Abstract: Abstract Here the synthesis, the molecular structure and the magnetic propertiesof four novel six-coordinated bis-dioxolene nickel and cobalt complexes with various di(pyridyl)imines as ancillary N-donor ligands is discussed. Despite the analogous composition the obtained compounds… read more here.
Keywords: bis dioxolene; cobalt iii; bis; nickel cobalt ... See more keywords
An insight to the spin density distribution and non-covalent interactions in a carboxylate bridged class-I mixed valence cobalt(II),cobalt(III) complex of quadruplet nature
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2021.120298
Abstract: Abstract A dinuclear mixed valence cobalt(II),cobalt(III) complex has been synthesized using a hexa-dentate (N2O4 donor) compartmental 'reduced Schiff base' ligand, and thiocyanate and 4-methyl-3-nitrobenzonate as anionic co-ligands. The complex has been characterized by spectroscopic measurements… read more here.
Keywords: cobalt; cobalt iii; spin; density distribution ... See more keywords
Synthesis, crystal structure, Hirshfeld surface analysis, spectroscopic characterizations and electrical properties of the new complex of cobalt (III) and the Schiff-base of dihydroxycoumarin
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2021.131161
Abstract: Abstract A new cobalt (III) complex, the [3,3′-{ethane-1,2-diylbis[(azanylylidene)eth-1-yl-1-ylidene]}bis [4-(hydroxy)-2H-1-benzopyran-2-onato]]-[bis(pyridine)]-cobalt chloradioxirane-1,1-dione hydrate, promising for its fluorescent and electrical properties was synthesized by the reaction of the Schiff-base '4-hydroxy-3-((E)-1-(2-((E)-1-(4-hydroxy-2-oxo-2H-chromen-3-yl)ethylideneamino) ethylimino) ethyl)-2H-chromene-2-one' and cobalt(II) acetate tetrahydrate under an… read more here.
Keywords: electrical properties; cobalt; hirshfeld surface; cobalt iii ... See more keywords
Synthesis, characterization and phenoxazinone synthase mimicking activity of cobalt(III) Schiff base complexes
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2016.10.027
Abstract: Abstract Three new mononuclear cobalt(III) complexes, [Co(L1)2]ClO4·2H2O (1) {HL1 = 2((2(2-hydroxyethylamino)ethylimino)methyl)-6-methoxyphenol}, [Co(L2)(acna)(N3)] (2) {HL2 = 2((2(2-hydroxyethylamino)ethylimino)methyl)-6-ethoxyphenol, Hacna = 2-acetyl-1-naphthol} and [Co(L3)(bzan)(N3)] (3) {HL3 = 1((2(diethylamino)ethylimino)methyl)naphthalen-2-ol, Hbzan = 1-benzoylacetone} were prepared and characterized by elemental and spectral analysis. The structures of all complexes were confirmed by… read more here.
Keywords: cobalt; characterization phenoxazinone; ethylimino methyl; cobalt iii ... See more keywords