Coupling Ruthenium Bipyridyl and Cobalt Imidazolate Units in a Metal-Organic Framework for an Efficient Photosynthetic Overall Reaction in Diluted CO2.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c01640
Abstract: Artificial photocatalytic CO2 reduction, using water as the reductant, is challenging mainly because it is difficult for multiple functional units to cooperate efficiently. Here, we show that the classic photosensitive and H2O-oxidizing ruthenium bipyridyl units… read more here.
Keywords: cobalt imidazolate; imidazolate units; organic framework; metal organic ... See more keywords
Control over the synthesis of homovalent and mixed-valence cubic cobalt-imidazolate cages.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc02083g
Abstract: A series of cubic cobalt-imidazolate cages have been successfully synthesized via subcomponent self-assembly in different solvents under solvothermal conditions. The homovalent CoII and mixed-valence CoIII,II-imidazolate cages are assembled with control over the mixed solvent ratio… read more here.
Keywords: cubic cobalt; imidazolate cages; cobalt imidazolate; mixed valence ... See more keywords