Synthesis and Reactivity of Cobalt(I) and Iridium(I) Complexes Bearing a Pentadentate N-Homoallyl-Substituted Bis(NHC) Pincer Ligand
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DOI: 10.1021/acs.organomet.0c00018
Abstract: Two methods for the synthesis of the bis(imidazolin-2-ylidene)carbazolide cobalt(I) complex [Co(bimcaHomo)] (2) have been developed. The first route relies on the direct transmetalation of the in s... read more here.
Keywords: cobalt; reactivity cobalt; cobalt iridium; iridium complexes ... See more keywords
Reductive Radical Conjugate Addition of Alkyl Electrophiles Catalyzed by a Cobalt/Iridium Photoredox System.
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DOI: 10.1021/acs.orglett.1c02114
Abstract: Alkyl and aryl halides have been studied extensively as radical precursors; however, mild and less toxic conditions for the activation of alkyl bromides toward alkyl radicals are still desirable. Reported here is a reductive radical… read more here.
Keywords: alkyl; radical conjugate; conjugate addition; reductive radical ... See more keywords