Highly Selective Hydroboration of Terminal Alkenes Catalyzed by a Cobalt Pincer Complex Featuring a Central Reactive N-Heterocyclic Phosphido Fragment
Sign Up to like & getrecommendations! Published in 2021 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00741
Abstract: The application of a cobalt pincer complex, (PPClP)CoCl2, as a precatalyst for the hydroboration of terminal alkenes with pinacolborane (HBPin) is described. The reactions proceed rapidly under mil... read more here.
Keywords: cobalt pincer; pincer complex; terminal alkenes; hydroboration terminal ... See more keywords
Cobalt Pincer Complexes in Catalytic C-H Borylation: The Pincer Ligand Flips Rather Than Dearomatizes.
Sign Up to like & getrecommendations! Published in 2018 at "ACS catalysis"
DOI: 10.1021/acscatal.8b03146
Abstract: The mechanism for the borylation of an aromatic substrate by a cobalt pincer complex was investigated by density functional theory calculations. Experimental observations identified trans-(iPrPNP)CoH2(BPin) as the resting state in the borylation of five-membered heteroarenes,… read more here.
Keywords: pincer; borylation; cobalt pincer; catalytic borylation ... See more keywords
Cobalt pincer-type complexes demonstrating unique selectivity for the hydroboration reaction of olefins under mild conditions
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic Chemistry Frontiers"
DOI: 10.1039/d3qi00478c
Abstract: Pincer cobalt complexes based on a triazine backbone have been used as efficient catalysts for the hydroboration reaction of alkenes. The presented protocol shows unique selectivity distinguishing a vinylsilyl from another alkenyl or alkynyl groups. read more here.
Keywords: cobalt pincer; hydroboration reaction; unique selectivity;