Visible-Light-Driven Selective Reduction of CO2 by Acetylene-Bridged Cobalt Porphyrin Conjugated Polymers.
Sign Up to like & getrecommendations! Published in 2022 at "ChemSusChem"
DOI: 10.1002/cssc.202200424
Abstract: Photocatalytic conversion of CO2 into renewable fuels with high efficiency and selectivity is desirable for solar energy utilization, but remains a great challenge. Herein, cobalt(II)-porphyrin functionalized conjugated polymers with acetylene bridging units, which are assembled… read more here.
Keywords: conjugated polymers; co2; cobalt porphyrin; acetylene ... See more keywords
Deciphering the Selectivity of the Electrochemical CO2 Reduction to CO by a Cobalt Porphyrin Catalyst in Neutral Aqueous Solution: Insights from DFT Calculations
Sign Up to like & getrecommendations! Published in 2023 at "ChemistryOpen"
DOI: 10.1002/open.202200254
Abstract: Abstract Density functional theory (DFT) calculations were conducted to investigate the cobalt porphyrin‐catalyzed electro‐reduction of CO2 to CO in an aqueous solution. The results suggest that CoII−porphyrin (CoII−L) undertakes a ligand‐based reduction to generate the… read more here.
Keywords: cobalt porphyrin; coii; reduction; co2 ... See more keywords
Electroluminescence and Photoluminescence from a Fluorescent Cobalt Porphyrin Grafted on Graphene Oxide
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Electronic Materials"
DOI: 10.1007/s11664-017-5627-1
Abstract: A new graphene oxide–cobalt porphyrin (GO–CoTPP) hybrid material has been used as an emissive layer in organic light-emitting diodes (OLEDs). Devices with fundamental structure of indium-doped tin oxide (ITO)/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS, 45 nm)/polyvinylcarbazole (PVK):2-(4-biphenyl)-5-(4-t-butylphenyl)-1,3,4-oxadiazole (PBD):GO–CoTPP (70 nm)/1,3,5-tris(N-phenylbenzimidazol-2-yl)-benzene (TPBI,… read more here.
Keywords: graphene oxide; grafted graphene; cotpp; cobalt porphyrin ... See more keywords
Highly Oxidized Cobalt Porphyrin Dimer: Control of Spin Coupling via a Bridge.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03807
Abstract: A cobalt porphyrin dimer is constructed in which two Co(II)porphyrins are connected covalently through a redox-active diethylpyrrole moiety via a flexible but "nonconjugated" methylene bridge. Upon oxidation with even a mild oxidant such as iodine,… read more here.
Keywords: cobalt porphyrin; cobalt; highly oxidized; bridge ... See more keywords
Re-Investigation of Cobalt Porphyrin for Electrochemical Water Oxidation on FTO Surface: Formation of CoOx as Active Species
Sign Up to like & getrecommendations! Published in 2017 at "ACS Catalysis"
DOI: 10.1021/acscatal.6b01815
Abstract: The use of cobalt porphyrin complexes as efficient and cost-effective molecular catalysts for water oxidation has been investigated previously. However, by combining a set of analytical techniques (electrochemistry, ultraviolet–visible spectroscopy (UV–vis), scanning electron microscopy (SEM),… read more here.
Keywords: cobalt porphyrin; water oxidation; spectroscopy;
Highly Efficient and Selective Photocatalytic CO2 Reduction to CO in Water by a Cobalt Porphyrin Molecular Catalyst
Sign Up to like & getrecommendations! Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b04975
Abstract: The performance of a water-soluble cobalt porphyrin ([{meso-tetra(4-sulfonatophenyl)porphyrinato}cobalt(III)], CoTPPS) as a catalyst for the photoreduction of CO2 in fully aqueous media has been investigated under visible light irradiation using [Ru(bpy)3]2+ as a photosensitizer and ascorbate… read more here.
Keywords: cobalt; co2; cobalt porphyrin; water ... See more keywords
Biomimetic Aerobic Epoxidation of Alkenes Catalyzed by Cobalt Porphyrin under Ambient Conditions in the Presence of Sunflower Seeds Oil as a Co-Substrate
Sign Up to like & getrecommendations! Published in 2020 at "ACS Omega"
DOI: 10.1021/acsomega.9b03714
Abstract: In this work, a mild and sustainable catalytic aerobic epoxidation of alkenes catalyzed by cobalt porphyrin was performed in the presence of sunflower seeds oil. Under ambient conditions, the conversion rate of trans-stilbene reached 99%,… read more here.
Keywords: alkenes catalyzed; aerobic epoxidation; epoxidation; epoxidation alkenes ... See more keywords
Accessing three oxidation states of cobalt in M6L3 nanoprisms with cobalt-porphyrin walls.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc04860k
Abstract: Nanocages with porphyrin walls are common, but studies of such structures hosting redox-active metals are rare. Pt2+-linked M6L3 nanoprisms with cobalt-porphyrin walls were prepared and their redox properties were evaluated electrochemically and chemically, leading to… read more here.
Keywords: porphyrin walls; m6l3 nanoprisms; cobalt porphyrin; nanoprisms cobalt ... See more keywords
Investigation of Molecular Mechanism of Cobalt Porphyrin Catalyzed CO2 Electrochemical Reduction in Ionic Liquid by In-Situ SERS
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28062747
Abstract: This study explores the electrochemical reduction in CO2 using room temperature ionic liquids as solvents or electrolytes, which can minimize the environmental impact of CO2 emissions. To design effective CO2 electrochemical systems, it is crucial… read more here.
Keywords: electrochemical reduction; reduction; co2 electrochemical; cobalt porphyrin ... See more keywords