Binding of Cobaltocenium-Containing Polyelectrolytes with Anionic Probes
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Inorganic and Organometallic Polymers and Materials"
DOI: 10.1007/s10904-017-0561-5
Abstract: Cationic cobaltocenium-containing polyelectrolytes have a unique ability to form ionic complex with various anionic species. We carried out two sets of model study to compare the relative binding strength of a cobaltocenium-containing polyelectrolyte. First, the… read more here.
Keywords: cobaltocenium; containing polyelectrolytes; cobaltocenium containing; anionic probes ... See more keywords
Stability Analysis of Substituted Cobaltocenium [Bis(cyclopentadienyl)cobalt(III)] Employing Chemistry-Informed Neural Networks.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of chemical theory and computation"
DOI: 10.1021/acs.jctc.1c01201
Abstract: Cationic cobaltocenium derivatives are promising components of the anion exchange membranes because of their excellent thermal and alkaline stability under the operating conditions of a fuel cell. Here, we present an efficient modeling approach to… read more here.
Keywords: chemistry informed; chemistry; substituted cobaltocenium; cobaltocenium ... See more keywords
Curious Case of Cobaltocenium Carbaldehyde
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DOI: 10.1021/acs.organomet.2c00613
Abstract: Cobaltocenium carbaldehyde (formylcobaltocenium) hexafluoridophosphate, a long sought-after functionalized cobaltocenium salt, is accessible from cobaltocenium carboxylic acid by a three-step synthetic sequence involving (i) chlorination to the acid chloride, (ii) copper-borohydride reduction to the hydroxymethyl derivative,… read more here.
Keywords: cobaltocenium carbaldehyde; carbaldehyde; curious case; spectroscopy ... See more keywords
Direct Amination of Cobaltocenium Hexafluoridophosphate via Vicarious Nucleophilic Substitution
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DOI: 10.1021/acs.organomet.9b00205
Abstract: In this communication we report a convenient, as short as possible synthesis of aminocobaltocenium hexafluoridophosphate, a very useful compound for further functionalization in cobaltocenium chemistry. Via vicarious nucleophilic substitution of hydrogen of cobaltocenium hexafluoridophosphate with… read more here.
Keywords: vicarious nucleophilic; hexafluoridophosphate; via vicarious; nucleophilic substitution ... See more keywords