Dynamic Metal-Iodide Bonds in a Tetracoordinated Cadmium-Based Metal-Organic Framework Boosting Efficient CO2 Cycloaddition under Solvent- and Cocatalyst-Free Conditions.
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DOI: 10.1021/acs.inorgchem.2c00569
Abstract: Due to the inherent thermodynamic stability and kinetic inertness of CO2, heterogeneous catalytic conversion of CO2 to cyclic carbonates often requires harsh operating conditions, high temperature and high pressure, and the addition of cocatalysts. Therefore,… read more here.
Keywords: mof; efficient co2; co2 cycloaddition; cocatalyst free ... See more keywords