Articles with "cocatalyst free" as a keyword



Cocatalyst‐Free Conversion of CO₂ to Cyclic Carbonates Using a Postsynthetically Modified Trifunctional Cu‐MOF

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Published in 2025 at "ChemCatChem"

DOI: 10.1002/cctc.202500684

Abstract: Carbon capture and conversion (CCC) into value‐added products offers a dual benefit of mitigating CO₂ emissions while generating industrially relevant chemicals. The cycloaddition of CO₂ with epoxides to form cyclic carbonates is among the most… read more here.

Keywords: conversion; mof; postsynthetically modified; cyclic carbonates ... See more keywords

Dynamic Metal-Iodide Bonds in a Tetracoordinated Cadmium-Based Metal-Organic Framework Boosting Efficient CO2 Cycloaddition under Solvent- and Cocatalyst-Free Conditions.

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Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c00569

Abstract: Due to the inherent thermodynamic stability and kinetic inertness of CO2, heterogeneous catalytic conversion of CO2 to cyclic carbonates often requires harsh operating conditions, high temperature and high pressure, and the addition of cocatalysts. Therefore,… read more here.

Keywords: mof; efficient co2; co2 cycloaddition; cocatalyst free ... See more keywords