Cationic Ruthenium (II)-NHC Pincer Complexes with Hemilabile COD: Solid-state Structural Characterisation and Theoretical Study of an η2-(E,Z)-COD Ligand
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DOI: 10.1016/j.jorganchem.2021.122061
Abstract: Abstract Cationic Ru(II)-CNC pincer complexes (CNC = 2,6-bis(1-methylimidazol-2-ylidene)pyridine), [Ru(CNC)(η2:η2-COD)Cl]Cl (1a) (COD = 1,5-cyclooctadiene), [Ru(CNC)(η2:η2-COD)Cl]PF6 (1b), [Ru(CNC)(η2-COD)Cl2] (2), [Ru(CNC)(DMSO)2Cl]Cl (3a), and [Ru(CNC)(DMSO)2Cl]PF6 (3b) have been synthesised and characterised. Single-crystal x-ray diffraction studies of the complexes reveal that the COD ligand… read more here.
Keywords: cnc; cod; solid state; pincer complexes ... See more keywords