Ruthenacyclopentanes as Intermediates in the Regio- and Stereoselective Linear Codimerization of N-Vinylamides with Electron-Deficient Alkenes
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DOI: 10.1021/acs.organomet.7b00545
Abstract: Tricarbonylruthenacyclopentanes were successfully synthesized by in situ reduction of RuCl3 with Zn-Cu/CO in the presence of N-vinylacetamides and electron-deficient alkenes such as ethyl acrylate, dimethyl fumarate, and dimethyl maleate. X-ray crystallography of the ruthenacyclopentanes revealed… read more here.
Keywords: codimerization; deficient alkenes; linear codimerization; ruthenacyclopentanes intermediates ... See more keywords