Deciphering the Selectivity of the Electrochemical CO2 Reduction to CO by a Cobalt Porphyrin Catalyst in Neutral Aqueous Solution: Insights from DFT Calculations
Sign Up to like & getrecommendations! Published in 2023 at "ChemistryOpen"
DOI: 10.1002/open.202200254
Abstract: Abstract Density functional theory (DFT) calculations were conducted to investigate the cobalt porphyrin‐catalyzed electro‐reduction of CO2 to CO in an aqueous solution. The results suggest that CoII−porphyrin (CoII−L) undertakes a ligand‐based reduction to generate the… read more here.
Keywords: cobalt porphyrin; coii; reduction; co2 ... See more keywords
3D Networks of CoFePi with Hierarchical Porosity for Effective OER Electrocatalysis.
Sign Up to like & getrecommendations! Published in 2018 at "Small"
DOI: 10.1002/smll.201704403
Abstract: A series of amorphous 3D Co-based phosphate networks with hierarchical porosity, including the CoPi, the binary CoM1 Pi and the trinary CoM1 M2 Pi (Mi = NiII , FeIII , CeIII ) are produced via… read more here.
Keywords: porosity; phosphate networks; hierarchical porosity; coii ... See more keywords
Redox-Induced Structural Switching through Sporadic Pyridine-Bridged CoIICoII Dimer and Electrocatalytic Proton Reduction.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00911
Abstract: The homodinuclear CoII helicate complex [CoII(DQPD)]2 (1) was prepared by treating [Co(H2O)6](ClO4)2 with the deprotonated form of the ligand N2,N6-bis(quinolin-8-yl)pyridine-2,6-dicarboxamide (DQPDH2). Complex 1 represents a discrete homodinuclear helicate complex with two CoII centers having a… read more here.
Keywords: pyridine; proton reduction; electrocatalytic proton; proton ... See more keywords
Synthetic Approaches to Metallo-Supramolecular CoII Polygons and Potential Use for H2O Oxidation.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02182
Abstract: Metal-directed self-assembly has been applied to prepare supramolecular coordination polygons which adopt tetrahedral (1) or trigonal disklike topologies (2). In the solid state, 2 assembles into a stable halide-metal-organic material (Hal-MOM-2), which catalyzes H2O oxidation… read more here.
Keywords: approaches metallo; h2o oxidation; oxidation; metallo supramolecular ... See more keywords
Bifunctional Sensors Based on Phosphomolybdates for Detection of Inorganic Hexavalent Chromium and Organic Tetracycline.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02016
Abstract: Exploring effective sensors for detecting possible hazards in a water system are greatly significant. This work proposed a strategy for stable and effective bifunctional sensors via incorporating hourglass-type phosphomolybdates into metal-organic fragments to construct a… read more here.
Keywords: bifunctional sensors; tetracycline; detection; coii ... See more keywords
Host-Guest Chemistry in Discrete Polyoxo-12-Palladate(II) Cubes [MO8Pd12L8]n- (M = ScIII, CoII, CuII, L = AsO43 -; M = CdII, HgII, L = PhAsO32-): Structure, Magnetism, and Catalytic Hydrogenation.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02751
Abstract: A family of five host-guest assemblies comprising different metal ions inside a cuboid 12-palladium-oxo cage, [MO8Pd12L8]n- (MPd12L8, M = ScIII, CoII, CuII, L = AsO43-; M = CdII, HgII, L = PhAsO32-), was synthesized and… read more here.
Keywords: host guest; spectroscopy; chemistry; coii cuii ... See more keywords
Nitric Oxide Oxygenation Reactions of Cobalt-Peroxo and Cobalt-Nitrosyl Complexes.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00639
Abstract: Here, we report a comparative study of nitric oxide oxidation (NOO) reactions of CoIII-peroxo (CoIII-O22-) and Co-nitrosyl ({CoNO}8) complexes bearing the same N4-donor ligand (HMTETA) framework. In this regard, we prepared and characterized two new… read more here.
Keywords: noo reactions; nitric oxide; coii; oxide oxygenation ... See more keywords
Construction and Magnetic Difference of {CoIIICoII12MII6} (M = CoII/CdII) Aggregates with Homo- and Heterometallic Centers Derived from {Co14} Precursors.
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.4c04083
Abstract: Controllable synthesis of sophisticated aggregations has attracted wide attention from scientists. In this work, homo- and heterometallic {CoIIICoII12MII6} (M = CoII/CdII) aggregates with similar skeletons, composed of two [Co3M3(dpbt)3] peripheries and a central [Co7(OH)8] vertex-fused… read more here.
Keywords: cdii aggregates; coiiicoii12mii6 coii; homo heterometallic; coii cdii ... See more keywords
Position Assignment and Oxidation State Recognition of Fe and Co Centers in Heterometallic Mixed-Valent Molecular Precursors for the Low-Temperature Preparation of Target Spinel Oxide Materials.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b01032
Abstract: A series of mixed-valent, heterometallic (mixed-transition metal) diketonates that can be utilized as prospective volatile single-source precursors for the low-temperature preparation of MxM'3-xO4 spinel oxide materials is reported. Three iron-cobalt complexes with Fe/Co ratios of… read more here.
Keywords: temperature preparation; low temperature; coii hfac; coii ... See more keywords
Tuning Bro̷nsted Acidity by up to 12 pKa Units in a Redox-Active Nanopore Lined with Multifunctional Metal Sites.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c15873
Abstract: Electrostatic interactions, hydrogen bonding, and solvation effects can alter the free energies of ionizable functional groups in proteins and other nanoporous architectures, allowing such structures to tune acid-base chemistry to support specific functions. Herein, we… read more here.
Keywords: chemistry; bro nsted; metal sites; coii ... See more keywords
Light-harvesting, 3rd generation RuII/CoII MOF with a large, tubular channel aperture.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc00206e
Abstract: A photoactive, hetero-metallic CoII/RuII-based metal-organic framework (MOF) with a large channel aperture, ca. 21 Å, is reported. The photophysical properties of the MOF are derived from the RuII nodes giving rise to emission centred at… read more here.
Keywords: coii; mof large; channel aperture; ruii ... See more keywords