Coligand effects on the architectures and magnetic properties of octahedral cobalt(ii) complexes with easy-axis magnetic anisotropy
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DOI: 10.1039/c9ce01871a
Abstract: Two mononuclear azido–cobalt(II) complexes, with the formulas [Co(3,3-Hbpt)2(N3)2(H2O)2] (1) and [Co(abpt)2(N3)2]·H2O (2) (3,3-Hbpt = 1H-3,5-bis(3-pyridyl)-1,2,4-triazole; abpt = 4-amino-3,5-bis(2-pyridyl)-1,2,4-triazole), have been prepared by altering the pyridyl-triazole coligands. In both complexes, the Co(II) centers feature hexa-coordinated environments… read more here.
Keywords: coligand effects; pyridyl triazole; cobalt complexes; axis magnetic ... See more keywords