Electrochemical collective synthesis of labeled pyrroloindoline alkaloids with Freon-type methanes as functional C1 synthons.
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DOI: 10.1039/d2cc03301a
Abstract: Utilization of Freon-type methanes as functional one-carbon synthons in the synthesis of various deuterated indoline alkaloids was demonstrated here. A series of halomethyl radicals were generated from electro-reductive C-X cleavage of Freon-type methanes and captured… read more here.
Keywords: type methanes; collective synthesis; methanes functional; electrochemical collective ... See more keywords
Collective synthesis of aspulvinone and its analogues by vinylogous aldol condensation of substituted tetronic acids with aldehydes
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DOI: 10.1039/d2ra08133d
Abstract: A mild, modular and efficient synthetic method with broad substrate scope was developed for aspulvinones. Nine natural aspulvinones were synthesized, six of which were for the first time. The aldol condensation delivered Z-configuration products predominantly… read more here.
Keywords: synthesis aspulvinone; condensation; collective synthesis; aspulvinone analogues ... See more keywords