Collective total synthesis of botryanes
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DOI: 10.1016/j.tet.2018.11.019
Abstract: Abstract The collective total synthesis of a series of botryanes, which are an important group of sesquiterpene antibiotics isolated from the metabolites of the fungus Botrytis cinerea, has been reported. The highly functionalized hydrindane skeleton… read more here.
Keywords: collective total; total synthesis; synthesis; synthesis botryanes ... See more keywords
Stereoselective addition of Grignard reagents to sulfinimines derived from tartrate diol (threitol): Generation of chiral building blocks for the collective total synthesis of lentiginosine, conhydrine and methyldihydropalustramate
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DOI: 10.1016/j.tet.2019.130496
Abstract: Abstract A systematic investigation of the addition of Grignard reagents to sulfinimines derived from tartaric acid diol was undertaken. It was observed that the chirality of the inherent tartrate moiety influences the diastereoselectivity of the… read more here.
Keywords: sulfinimines derived; addition grignard; building blocks; collective total ... See more keywords
Collective Total Syntheses of Benzo[c]phenanthridine Alkaloids via a Sequential Transition Metal-Catalyzed Pot-Economic Approach.
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DOI: 10.1021/acs.orglett.2c03278
Abstract: Collective total syntheses of 10 benzo[c]phenanthridines were achieved on the basis of the construction of rings C and B through sequential transition metal-catalyzed reactions and flexible condition-controlled Mannich reaction via three pots in 25-34% yields,… read more here.
Keywords: sequential transition; transition metal; total syntheses; syntheses benzo ... See more keywords