Stereospecific Dehydroxytrifluoromethylthiolation of Alcohols Promoted by a Combination of Hypervalent Trifluoromethylthio-iodine(III) Reagent and N-Heterocyclic Carbene.
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DOI: 10.1021/acs.orglett.3c00641
Abstract: Direct dehydroxytrifluoromethylthiolation of alcohols is an attractive strategy for accessing CF3S-containing compounds. Herein, we report a method for dehydroxytrifluoromethylthiolation of alcohols by using the combination of hypervalent iodine(III) reagent TFTI and N-heterocyclic carbenes. This method… read more here.
Keywords: combination hypervalent; iodine iii; dehydroxytrifluoromethylthiolation; dehydroxytrifluoromethylthiolation alcohols ... See more keywords