Comment on "Cage occupancy of methane clathrate hydrates in the ternary H2O-NH3-CH4 system" by C. Petuya, M. Choukroun, T. H. Vu, A. Desmedt, A. G. Davies, and C. Sotin, Chem. Commun., 2020, 56, 12391.
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DOI: 10.1039/d1cc06526b
Abstract: Alternative interpretations of the experimental results given in the Communication of Petuya et al.1 are presented. There is evidence that under certain conditions, ammonia can be incorporated into clathrate hydrate cages. read more here.
Keywords: clathrate; methane clathrate; clathrate hydrates; occupancy methane ... See more keywords
Reply to the 'Comment on Cage occupancy of methane clathrate hydrates in the ternary H2O-NH3-CH4 system' by S. Alavi and J. Ripmeester, Chem. Commun., 2022, 58, DOI: 10.1039/D1CC06526B.
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DOI: 10.1039/d2cc00568a
Abstract: Our recent Communication suggested that ammonia in aqueous solution may preferentially destabilize large cages in methane clathrate hydrates. A Comment favored ammonia incorporation instead, but it did not accurately describe our proposed mechanism and relied… read more here.
Keywords: methane clathrate; clathrate hydrates; cage occupancy; comment cage ... See more keywords