Microwave synthesis of charge-compensated dodecaborates bearing exohedral boron-phosphorus connectivities
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.12.027
Abstract: Abstract Solution pyrolysis of arylphosphonium salts of B12H122−,1, utilizing microwave heating provided charge-compensated monophosphine dodecaborate derivatives of general formula B12H11(PPhnR3-n)− (n = 1, R = Me; n = 2, R = Me, Et) in high yield. The resulting anions B12H11(PPh2Me)− (2), B12H11(PPhMe2)− (3),… read more here.
Keywords: compensated dodecaborates; charge; synthesis charge; microwave synthesis ... See more keywords