Competition of Hydrogen Bonds and Coordinate Bonds Induces a Reversible Crystal Transformation.
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DOI: 10.1021/acs.inorgchem.1c03291
Abstract: Achieving reversible molecular crystal transformation between coordinate aggregates and hydrogen bonded assemblies has been a challenging task because coordinate bonds are generally much stronger than hydrogen bonds. Recently, we have reported the incorporation of silver… read more here.
Keywords: hydrogen bonds; coordinate bonds; hydrogen; competition hydrogen ... See more keywords
The Competition between Hydrogen, Halogen, and Covalent Bonding in Atmospherically Relevant Ammonium Iodate Clusters.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c10841
Abstract: Iodine-containing clusters are expected to be central to new particle formation (NPF) events in polar and midlatitude coastal regions. Iodine oxoacids and iodine oxides are observed in newly formed clusters, and in more polluted midlatitude… read more here.
Keywords: halogen covalent; hydrogen halogen; competition hydrogen; covalent bonding ... See more keywords
Competition between hydrogen bonds and halogen bonds: a structural study
Sign Up to like & getrecommendations! Published in 2018 at "New Journal of Chemistry"
DOI: 10.1039/c8nj00537k
Abstract: The competition and balance between intermolecular hydrogen bonds (HBs) and halogen bonds (XBs) were explored by co-crystallizing tetra-functionalized (2 × HB (–OH) and 2 × XB (–CC–I)) molecules, trans-1,4-bis(iodoethynyl)cyclohexane-1,4-diol (D1) and cis-1,4-bis(iodoethynyl)cyclohexane-1,4-diol (D2), with six… read more here.
Keywords: hydrogen; hydrogen bonds; bonds halogen; competition hydrogen ... See more keywords