Nickel-assisted complete cleavage of CO by a silylene/siliconoid hybrid under formation of an Si[double bond, length as m-dash]C enol ether bridge.
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DOI: 10.1039/d0cc04922k
Abstract: Reaction of a silylene-functionalized Si6 siliconoid with CO in the presence of catalytic quantities of a nickel(0) complex results in the complete cleavage of the CO triple bond, but preserves the Si6 scaffold with an… read more here.
Keywords: length dash; dash enol; bond; bond length ... See more keywords