Synthesis of Complex Boron-Nitrogen Heterocycles Comprising Borylated Triazenes and Tetrazenes Under Mild Conditions.
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DOI: 10.1021/jacs.9b12336
Abstract: The reactions of organic azides with diaryl(dihalo)diboranes(4) were explored, resulting in the observation of a number of surprising reactivity patterns. The reaction of phenyl azide with 1,2-diaryl-1,2-dihalodiboranes(4) resulted in the formation of five-membered rings comprising… read more here.
Keywords: nitrogen; boron nitrogen; phenyl azide; complex boron ... See more keywords