Mo(VI) complex catalysed synthesis of sulfones and their modification for anti-HIV activities
Sign Up to like & getrecommendations! Published in 2020 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2020.105931
Abstract: Abstract An efficient method for the synthesis of sulfones has been developed using sugar derived cis-dioxo molybdenum(VI) complex as catalyst and urea hydrogen peroxide as oxygen source. Present method is highly specific for sulfide oxidation… read more here.
Keywords: synthesis sulfones; sulfones modification; modification anti; complex catalysed ... See more keywords
Aluminium complex-catalysed hydroboration of alkenes and alkynes
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DOI: 10.1039/c9nj01859j
Abstract: Catalytic hydroboration of terminal alkenes/alkynes with HBpin using the Al(III) catalyst, [κ2-{Ph2P(=Se)NCH2(C5H4N)}Al(CH3)2] (1), under mild and solvent-free conditions to afford corresponding alkyl/alkenyl boronate esters in high yield is reported. read more here.
Keywords: hydroboration alkenes; aluminium complex; alkenes alkynes; catalysed hydroboration ... See more keywords
Pd-N-heterocyclic carbene complex catalysed C–H bond activation of 2-isobutylthiazole at the C5 position with aryl bromides
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DOI: 10.1039/d1nj00514f
Abstract: An effective and efficient catalytic system has been reported for the synthesis of C5-arylated 2-isobutylthiazoles. read more here.
Keywords: catalysed bond; activation isobutylthiazole; bond activation; heterocyclic carbene ... See more keywords
Solvent-free Zn (NSNO) complex-catalysed dihydroboration of nitriles.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03517k
Abstract: N-donors are the most commonly employed Lewis bases in ligand-assisted catalysis. A dimeric zinc complex (Zn-1) employing a tetradentate pyridine-thioether-anilido-aryloxide NSNO ligand (L) effects the quantitative conversion of nitriles to the corresponding double hydroborated products… read more here.
Keywords: nsno complex; catalysed dihydroboration; solvent free; dihydroboration nitriles ... See more keywords