Manganese complex catalyst for valencene oxidation: The first use of metalloporphyrins for the selective production of nootkatone
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.120031
Abstract: Abstract This work describes the oxidation of valencene, a sesquiterpene easily obtained from citrus fruits, and responsible for the fresh odor of oranges. The reactions were catalyzed by manganese porphyrins derived from 5,10,15,20-tetrakis(3,5-dimethoxyphenyl)porphyrin (H2T3,5DMPP): [MnIII(T3,5DMPP)Cl]… read more here.
Keywords: complex catalyst; catalyst valencene; valencene oxidation; manganese complex ... See more keywords
Salicylaldimine-Ni complex supported on Al2O3: Highly efficient catalyst for hydrogen production from hydrolysis of sodium borohydride
Sign Up to like & getrecommendations! Published in 2018 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2017.10.151
Abstract: Abstract In this study, the Ni-based complex catalyst containing nickel of 1% supported on Al2O3 is used as for the hydrogen production from NaBH4 hydrolysis. The maximum hydrogen production rate from hydrolysis of NaBH4 with… read more here.
Keywords: catalyst; supported al2o3; hydrogen production; complex catalyst ... See more keywords
Effective TiO2 supported Cu-Complex catalyst in NaBH4 hydrolysis reaction to hydrogen generation
Sign Up to like & getrecommendations! Published in 2019 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2018.12.225
Abstract: Abstract This paper reports the experimental results on using TiO2 based Cu(II)-Schiff Base complex catalyst for hydrolysis of NaBH4. In the presence of Cu-Schiff Base complex which we reported in advance [1] and with titanium… read more here.
Keywords: hydrolysis; complex catalyst; catalyst; hydrogen ... See more keywords
Highly active and stable CeO2 supported nickel-complex catalyst in hydrogen generation
Sign Up to like & getrecommendations! Published in 2020 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2020.09.201
Abstract: Abstract Cerium oxide supported 5-Amino-2,4-dichlorophenol-3,5-ditertbutylsalisylaldimine-Nickel complex for the first time was used to produce H2 from hydrolysis of sodium borohydride. Cerium oxide supported Nickel complex catalyzed hydrolysis system was studied depend on temperature, concentration of… read more here.
Keywords: cerium oxide; complex catalyst; sodium; nickel complex ... See more keywords
Bidentate Ru(II)-NC Complex as a Catalyst for Semihydrogenation of Azoarenes to Hydrazoarenes with Ethanol.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02866
Abstract: The transfer hydrogenation of azoarenes to hydrazoarenes using ethanol as a hydrogen source by a bidentate Ru(II)-NC complex is developed. A weak base is crucial for this semihydrogenation that can efficiently avoid hydrazoarene dehydrogenation under… read more here.
Keywords: catalyst semihydrogenation; azoarenes hydrazoarenes; bidentate complex; complex catalyst ... See more keywords
Low-Energy Electrocatalytic CO2 Reduction in Water over Mn-Complex Catalyst Electrode Aided by a Nanocarbon Support and K+ Cations
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DOI: 10.1021/acscatal.8b01068
Abstract: Electrocatalytic CO2 reduction over a Mn-complex catalyst in an aqueous solution was achieved at very low energy with a combination of multiwalled carbon nanotubes (MWCNTs) and K+ cations. Although the bare Mn-complex did not function… read more here.
Keywords: co2; co2 reduction; electrocatalytic co2; complex catalyst ... See more keywords
Development of a Highly Durable Photocatalytic CO2 Reduction Using a Mn-Complex Catalyst: Application of Selective Photosplitting of a Mn(0)–Mn(0) Bond
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c18366
Abstract: fac-[MnI(diimine)(CO)3(L)]0/+ has attracted significant attention as a catalyst for the photocatalytic reduction of CO2. However, in such photocatalytic systems, the photoexcitation of Mn complexes and reaction intermediates induces their decomposition, which lowers the durability of… read more here.
Keywords: catalyst; co2; durable photocatalytic; reduction ... See more keywords
Visible-Light Activation of a Ru(II) Complex Catalyst via a Carbazole-Modified Donor–Acceptor Ligand for CO2 Reduction
Sign Up to like & getrecommendations! Published in 2024 at "Chemistry Letters"
DOI: 10.1093/chemle/upae127
Abstract: Visible-light activation of photocatalysts is crucial for effectively utilizing solar energy in molecular conversions. This study demonstrates that modifying the bipyridine ligand with carbazole enables visible-light activation of a Ru(II) carbonyl complex catalyst, which is… read more here.
Keywords: visible light; co2 reduction; ligand; light activation ... See more keywords