Conformational twisting of a formate-bridged diiridium complex enables catalytic formic acid dehydrogenation.
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DOI: 10.1039/c8dt03268h
Abstract: We previously reported that iridium complex 1a enables the first homogeneous catalytic dehydrogenation of neat formic acid and enjoys unusual stability through millions of turnovers. Binuclear iridium hydride species 5a, which features a provocative C2-symmetric… read more here.
Keywords: complex enables; acid dehydrogenation; dehydrogenation; formic acid ... See more keywords