An S = 1/2 Iron Complex Featuring N2, Thiolate, and Hydride Ligands: Reductive Elimination of H2 and Relevant Thermochemical Fe-H Parameters.
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DOI: 10.1021/jacs.8b02603
Abstract: Believed to accumulate on the Fe sites of the FeMo-cofactor (FeMoco) of MoFe-nitrogenase under turnover, strongly donating hydrides have been proposed to facilitate N2 binding to Fe and may also participate in the hydrogen evolution… read more here.
Keywords: hydride; iron complex; complex featuring; featuring thiolate ... See more keywords
A thiolate-bridged ruthenium-molybdenum complex featuring terminal nitrido and bridging amido ligands derived from the N-H and N-N bond cleavage of hydrazine.
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DOI: 10.1039/d2dt01378a
Abstract: Biomimetic di- or multimetallic complexes featuring NxHy species in a sulfur-rich coordination sphere have attracted considerable attention in modelling the possible scenarios of biological nitrogen fixation by nitrogenases. Although the active site of nitrogenases is… read more here.
Keywords: bridged ruthenium; complex featuring; molybdenum complex; hydrazine ... See more keywords
Thermodynamics of spin crossover in a bis(terpyridine) cobalt(II) complex featuring a thioether functionality.
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DOI: 10.1039/d4dt00574k
Abstract: In this contribution, a terpyridine-based ligand bearing a thioether functionality is used to prepare a new cobalt(II) spin crossover complex: [Co(TerpyPhSMe)2](PF6)2 (1), where TerpyPhSMe is 4'-(4-methylthiophenyl)-2,2':6',2''-terpyridine. Its structure, determined by single crystal X-ray diffraction, reveals… read more here.
Keywords: thioether functionality; thermodynamics; cobalt; spin crossover ... See more keywords