An S = 1/2 Iron Complex Featuring N2, Thiolate, and Hydride Ligands: Reductive Elimination of H2 and Relevant Thermochemical Fe-H Parameters.
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DOI: 10.1021/jacs.8b02603
Abstract: Believed to accumulate on the Fe sites of the FeMo-cofactor (FeMoco) of MoFe-nitrogenase under turnover, strongly donating hydrides have been proposed to facilitate N2 binding to Fe and may also participate in the hydrogen evolution… read more here.
Keywords: hydride; iron complex; complex featuring; featuring thiolate ... See more keywords
A thiolate-bridged ruthenium-molybdenum complex featuring terminal nitrido and bridging amido ligands derived from the N-H and N-N bond cleavage of hydrazine.
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DOI: 10.1039/d2dt01378a
Abstract: Biomimetic di- or multimetallic complexes featuring NxHy species in a sulfur-rich coordination sphere have attracted considerable attention in modelling the possible scenarios of biological nitrogen fixation by nitrogenases. Although the active site of nitrogenases is… read more here.
Keywords: bridged ruthenium; complex featuring; molybdenum complex; hydrazine ... See more keywords