Understanding Mechanochromic Luminescence on Account of Molecular Level Based on Phosphorescent Iridium(III) Complex Isomers.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c03515
Abstract: Mechanochromic luminescent (MCL) materials are promising in pressure sensors, security papers, photoelectric devices and optical data recording. Although some kinds of MCL-active iridium(III) complexes with various soft substituent functional ligands (e.g., dendritic carbazole, flexible chains,… read more here.
Keywords: mcl; iridium iii; iridium; iii complex ... See more keywords
6-Bromo-2-hydroxypyridinate-bridged Paddlewheel-Type Dirhodium Complex Isomers: Synthesis, Crystal Structures, Electrochemical Properties, and Structure-Dependent Absorption Properties
Sign Up to like & getrecommendations! Published in 2024 at "Inorganics"
DOI: 10.3390/inorganics12030070
Abstract: Two new paddlewheel-type dirhodium (Rh2) complex isomers, formulated as trans-2,2- and 3,1-forms of [Rh2(bhp)4] (bhp = 6-bromo-2-hydroxypyridinate), were obtained by the reaction of 6-bromo-2-hydroxypyridine with [Rh2(O2CCH3)4(H2O)2] and characterized by NMR, ESI-MS, and elemental analyses. Single… read more here.
Keywords: complex isomers; type dirhodium; structure; paddlewheel type ... See more keywords