A Nonheme Iron(III) Superoxide Complex Leads to Sulfur Oxygenation.
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DOI: 10.1021/jacs.3c12337
Abstract: A new alkylthiolate-ligated nonheme iron complex, FeII(BNPAMe2S)Br (1), is reported. Reaction of 1 with O2 at -40 °C, or reaction of the ferric form with O2•- at -80 °C, gives a rare iron(III)-superoxide intermediate, [FeIII(O2)(BNPAMe2S)]+… read more here.
Keywords: iron iii; iron; superoxide complex; complex leads ... See more keywords