Isolation of a [Fe(CO)4]2–-Bridged Diuranium Complex Obtained via Reduction of Fe(CO)5 with Uranium(III)
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DOI: 10.1021/acs.organomet.1c00205
Abstract: Treatment of the U(III) complex, [(C5Me5)2U(OMes)(THF)], Mes = 2,4,6-Me3C6H2, with Fe(CO)5 forms [{(C5Me5)2(MesO)U}2(μ2-(OC)2Fe(CO)2)] with the bridging, tetrahedral Fe(CO)4 moiety. This complex ha... read more here.
Keywords: iii; complex obtained; isolation bridged; diuranium complex ... See more keywords