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Cooperative Bond Activation Reactions with Ruthenium Carbene Complex PhSO2(Ph2PNSiMe3)C═Ru(p-cymene): Ru═C and N–Si Bond Reactivity

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Published in 2018 at "Organometallics"

DOI: 10.1021/acs.organomet.7b00254

Abstract: The synthesis of ruthenium carbene complex PhSO2(Ph2PNSiMe3)C═Ru(p-cymene) (3) and its application in cooperative bond activation reactions were studied. Compound 3 is accessible via salt metathesis using the dilithium methandiide ligand or alternatively via dehydrohalogenation of… read more here.

Keywords: bond; ruthenium carbene; carbene complex; complex phso2 ... See more keywords