A Mn(iv)-peroxo complex in the reactions with proton donors.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00649d
Abstract: Protons play an important role in promoting O-O or M-O bond cleavage of metal-peroxo complexes. Treatment of side-on O2-bound [PPN][MnIV(TMSPS3)(O2)] (1, PPN = bis(triphenylphosphine)iminium and TMSPS3H3 = 2,2',2''-trimercapto-3,3',3''-tris(trimethylsilyl)triphenylphosphine) with perchloric acid (HClO4) in the presence… read more here.
Keywords: complex reactions; proton donors; reactions proton; peroxo complex ... See more keywords
A virtual model for non-catalytic successive gas-solid reactions
Sign Up to like & getrecommendations! Published in 2017 at "Multidiscipline Modeling in Materials and Structures"
DOI: 10.1108/mmms-07-2016-0031
Abstract: Purpose Many of the industrially important processes follow a complex reaction scheme and more than one reaction takes place simultaneously for these systems. Design and scale up of these processes are important but due to… read more here.
Keywords: complex reactions; model; virtual model; modeling complex ... See more keywords