Multifunctional Dinuclear Dy-Based Coordination Complex Showing Visible Photoluminescence, Single-Molecule Magnet Behavior, and Proton Conduction.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02822
Abstract: A new Dy-based complex, [Dy2(phen)4(PAA)4](ClO4)2 (1), was obtained by using 4-hydroxyphenyl acetate (HPAA) as a ligand and 1,10-phenanthroline as an auxiliary ligand. Complex 1 shows a dinuclear structure and a 2D supramolecular layer constructed by… read more here.
Keywords: single molecule; behavior proton; proton conduction; complex showing ... See more keywords
Spin-crossover in an iron(III) complex showing a broad thermal hysteresis.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt03610b
Abstract: A pentadentate Schiff-base ligand 3,5Cl-L2- and NCSe- form an iron(iii) mononuclear complex, namely [Fe(3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99… read more here.
Keywords: complex showing; spin crossover; hysteresis; crossover iron ... See more keywords