A Phosphine-ß-diketiminate Nickel(I)-Complex for Small Molecule Activation.
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DOI: 10.1002/cplu.202200288
Abstract: A bis(diphenyl)-phosphine functionalized ß-diketimine ligand (PNac-H) was applied for the synthesis of a subvalent Ni(I) complex [PNac-Ni]. Here, the Ni(I) center is stabilized by a tetradentate PNNP-type pocket, forming a square planar coordination sphere. Subsequently,… read more here.
Keywords: phosphine; phosphine diketiminate; complex small; nickel complex ... See more keywords
Complex Small Supernumerary Marker Chromosome Leading to Partial 4q/21q Duplications: Clinical Implication and Review of the Literature
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DOI: 10.1159/000494682
Abstract: Complex small marker chromosomes (sSMCs) consist of chromosomal material derived from more than 1 chromosome. Complex sSMCs derived from chromosomes 4 and 21 are rare, with only 7 cases reported. Here, we describe a patient… read more here.
Keywords: marker chromosome; complex small; 21q duplications; chromosome ... See more keywords