Re-investigation of an octanuclear iron-oxo complex supported by 4- butyl-pyrazolido ligands
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.07.003
Abstract: Abstract The synthesis and characterization of the octanuclear all-ferric compounds [Fe8(μ4-O)4(μ-4-R-pz)12Cl4], R = tBu (1) and nBu (2) by spectroscopic (1H NMR, UV–Vis, FTIR, 57Fe-Mossbauer) and electrochemical methods are reported along with the single crystal X-ray structure… read more here.
Keywords: investigation octanuclear; iron oxo; supported butyl; octanuclear iron ... See more keywords
A five-coordinate Ni(I) complex supported by 1,4,7-triisopropyl-1,4,7-triazacyclononane.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02516g
Abstract: An isolated Ni(II)-nitrosyl complex supported by the bulky tridentate 1,4,7-triisopropyl-1,4,7-triazacyclononane (iPr3TACN) ligand was obtained from the reaction of a Ni(II) dimethyl complex with NOPF6, suggesting the in situ formation of a Ni(I) species that reacts… read more here.
Keywords: coordinate complex; triisopropyl triazacyclononane; complex supported;
A Cu(ii) complex supported on Fe3O4@SiO2 as a magnetic heterogeneous catalyst for the reduction of environmental pollutants
Sign Up to like & getrecommendations! Published in 2022 at "RSC Advances"
DOI: 10.1039/d2ra04787j
Abstract: Today, the presence of pollutants in the environment has become one of the serious problems and concerns of human beings. To eliminate these pollutants, researchers have made many efforts. One of the most important of… read more here.
Keywords: fe3o4 sio2; catalyst; spectroscopy; microscopy ... See more keywords
C(sp2)–H Iodination by a Rhodium(III) Complex Supported by a Redox-active Ligand Bearing Amidophenolato Moieties
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DOI: 10.1246/cl.200178
Abstract: C(sp2)–H iodination of m-xylene promoted by a rhodium(III) complex supported by a redox-active ligand, (nBu4N)[RhIIIL3−(MeCN)Cl] (1Cl), is reported. The iodination reaction involves an electrophili... read more here.
Keywords: iodination; supported redox; complex supported; sp2 iodination ... See more keywords