A Borane Platinum Complex Undergoing Reversible Hydride Migration in Solution.
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DOI: 10.1021/acs.inorgchem.7b02807
Abstract: Reaction of [Pt(κ2-C,N-ppy)(dmso)Cl], 1 (Hppy = 2-phenylpyridine), with Na[H2B(mb)2] (Hmb = 2-mercapto-benzimidazole) smoothly afforded the complex {[(κ3-S,B,S-HB(mb)2]Pt(κ2-C,N-ppy)H}, 2, featuring a strong reverse-dative Pt → B σ interaction in the solid state. When dissolved in thf… read more here.
Keywords: borane platinum; complex undergoing; solution; platinum complex ... See more keywords