Fluoride complexation by bidentate silicon Lewis acids.
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DOI: 10.1039/c6dt04608h
Abstract: Diethynyldiphenylsilane (1) and divinyldiphenylsilane (2) were functionalized by hydrosilylation reactions with HSiMe2Cl, HSiMeCl2 and HSiCl3. Fluorination of the resulting compounds generates bidentate open-chain Lewis acids of increasing acidity. All semi-flexible [Ph2Si(CH[double bond, length as m-dash]CHSiFnMe3-n)2… read more here.
Keywords: complexation bidentate; spectroscopy; lewis acids; bidentate ... See more keywords