Synthesis of strained complexes of arene d6 metals with benzoylthiourea and their spectral studies
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.05.023
Abstract: Abstract Halide bridged arene d6 platinum group metal precursors on treatment with thiourea derivatives (L1 and L2) yielded a series of neutral mono-dentate complexes (1–8). In general complexes have been formulated as [(arene)M(L)к1(S)Cl2] where L = L1,… read more here.
Keywords: arene metals; mono dentate; reaction complex; strained complexes ... See more keywords
Indenyl Rhodium Complexes with Arene Ligands: Synthesis and Application for Reductive Amination
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00311
Abstract: An efficient protocol for synthesis of indenyl rhodium complexes with arene ligands has been developed. The hexafluoroantimonate salts [(η5-indenyl)Rh(arene)](SbF6)2 (arene = benzene (2a), o-xylene (2b), mesitylene (2c), durene (2d), hexamethylbenzene (2e), and [2.2]paracyclophane (2g)) were… read more here.
Keywords: indenyl; rhodium complexes; indenyl rhodium; arene ligands ... See more keywords