Cationic Gold(I) Diarylallenylidene Complexes: Bonding Features and Ligand Effects
Sign Up to like & getrecommendations! Published in 2019 at "Chemphyschem"
DOI: 10.1002/cphc.201900411
Abstract: Abstract Using computational approaches, we qualitatively and quantitatively assess the bonding components of a series of experimentally characterized Au(I) diarylallenylidene complexes (N.Kim, R.A.Widenhoefer, Angew. Chem. Int. Ed. 2018, 57, 4722–4726). Our results clearly demonstrate that… read more here.
Keywords: diarylallenylidene; bonding features; gold diarylallenylidene; complexes bonding ... See more keywords
Sesquicarbene Complexes: Bonding at the Interface Between M–C Single Bonds and M═C Double Bonds
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DOI: 10.1021/acs.organomet.0c00102
Abstract: Allylic dimetalated complexes [M2C(vinyl)]+ (M = Au(IPr) and Cr(CO)5–) incorporate a new coordination mode of carbon. Digold complexes of this type have recently been detected experimentally. The i... read more here.
Keywords: interface single; bonding interface; single bonds; bonds double ... See more keywords