14-Electron Rh and Ir silylphosphine complexes and their catalytic activity in alkene functionalization with hydrosilanes.
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DOI: 10.1039/d1dt00677k
Abstract: Herein we report an experimental and computational study of a family of four coordinated 14-electron complexes of Rh(iii) devoid of agostic interactions. The complexes [X-Rh(κ3(P,Si,Si)PhP(o-C6H4CH2SiiPr2)2], where X = Cl (Rh-1), Br (Rh-2), I (Rh-3), OTf… read more here.
Keywords: silylphosphine complexes; electron silylphosphine; complexes catalytic; catalytic activity ... See more keywords