Hydrido-Cobalt Complexes for the Chemo- and Regioselective 1,2-Silylative Dearomatization of N-Heteroarenes.
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DOI: 10.1021/acs.orglett.3c00022
Abstract: We describe an efficient regio- and chemoselective dearomatization of N-heteroarenes using hydrido-cobalt catalysts. Reactions were performed under mild conditions on a wide range of N-heteroarenes leading exclusively to the silyl-1,2-dihydroheteroarene. Various quinolines and pyridines bearing… read more here.
Keywords: complexes chemo; dearomatization heteroarenes; hydrido cobalt; cobalt complexes ... See more keywords