(α-Diimine)nickel Complexes That Contain Menthyl Substituents: Synthesis, Conformational Behavior, and Olefin Polymerization Catalysis
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DOI: 10.1021/acs.organomet.7b00283
Abstract: We describe the synthesis and coordination chemistry of the (1R,2S,5R)-menthyl-substituted N,N′-diaryl-α-diimine ligands N,N′-(2-Men-4-Me-Ph)2-BIAN (L1, Men = menthyl, BIAN = bis(imino)acenaphthene) and N,N′-(2-Men-4,6-Me2-Ph)2-BIAN (L2), the conformational properties of these ligands and their metal complexes, and the… read more here.
Keywords: polymerization; complexes contain; nickel complexes; contain menthyl ... See more keywords
Syntheses of Molybdenum(VI) Imido Alkylidene Complexes That Contain a Bidentate Dithiolate Ligand
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DOI: 10.1021/acs.organomet.8b00614
Abstract: Zn(DCTC) (DCTC = 3,6-dichlorodithiacatecholate) reacts with Mo(NAd)(CHCMe2Ph)Cl2(PPh2Me) (Ad = 1-adamantyl) to give Mo(NAd)(CHCMe2Ph)(DCTC)(PPh2Me). The reactions between Zn(DCTC) and Mo(NAd)(CH-t-Bu)(OTf)2(dme) or Mo(NAr)(CHCMe2Ph)(OTf)2(dme) (Ar = 2,6-i-Pr2C6H3; OTf = triflate; dme = 1,2-dimethoxyethane) produce [Mo(NAd)(CH-t-Bu)(DCTC)]2 and [Mo(NAr)(CHCMe2Ph)(DCTC)]2, respectively.… read more here.
Keywords: nar chcme2ph; syntheses molybdenum; chcme2ph; complexes contain ... See more keywords