Ln(II) amido complexes coordinated by ring-expanded N-heterocyclic carbenes - promising catalysts for olefin hydrophosphination.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc05424k
Abstract: First Ln(ii) ring-expanded NHC complexes (er-NHC)Ln[N(SiMe3)2]2 (Ln = Sm, Yb) are synthesized and proved to be highly efficient pre-catalysts for the intermolecular hydrophosphination of such indolent substrates as 1-alkenes, cyclohexene and norbornene. read more here.
Keywords: coordinated ring; amido complexes; complexes coordinated; expanded heterocyclic ... See more keywords
Aggregation-induced enhanced fluorescence emission of chiral Zn(II) complexes coordinated by Schiff-base type binaphthyl ligands.
Sign Up to like & getrecommendations! Published in 2024 at "Dalton transactions"
DOI: 10.1039/d4dt00903g
Abstract: A pair of novel chiral Zn(II) complexes coordinated by Schiff-base type ligands derived from BINOL (1,1'-bi-2-naphthol), R-/S-Zn, were synthesized. X-ray crystallography revealed the presence of two crystallographically independent complexes; one has a distorted trigonal-bipyramidal structure… read more here.
Keywords: binaphthyl ligands; schiff base; coordinated schiff; complexes coordinated ... See more keywords
Synthesis, characterization and base hydrolysis of cobalt(III) complexes coordinated by substituted phenylthioether ligands
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DOI: 10.1071/ch24012
Abstract: A synthetic route to the preparation of cobalt(III) complexes coordinated by bidentate phenylthioether ligands is described. Complexes of the type ((2-(X-phenylthio)ethylamine)-N,S)bis(ethylenediamine)cobalt(III) perchlorate, [(en)2Co(S(X-phenyl)CH2CH2NH2)](ClO4)3, where X = 4-methoxy (2a), 4-methyl (2b), 3-methyl (2c), nothing (2d), 3-methoxy (2e), 4-bromo… read more here.
Keywords: spectroscopy; cobalt; cobalt iii; iii complexes ... See more keywords