Zinc Complexes with Cyanoxime: Structural, Spectroscopic, and Catalysis Studies in the Pivaloylcyanoxime-Zn System.
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DOI: 10.1021/acs.inorgchem.7b01891
Abstract: Reaction of 2-hydroxyimino-4,4-dimethyl-3-oxo-pentanenitrile (common abbreviation HPiCO, pivaloyl-cyanoxime) with zinc sulfate in an aqueous solution results in the formation of the two new complexes: [Zn(PiCO){H(PiCO)2}(H2O)] (I) and tetranuclear Zn complex [Zn4(μ3-OH)2(PiCO)6 (H2O)4] (II). Both complexes were… read more here.
Keywords: zinc; zinc complexes; catalysis; complexes cyanoxime ... See more keywords