Synthesis, structures and photoluminescence properties of silver complexes of cyclic (alkyl)(amino)carbenes ☆
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DOI: 10.1016/j.jorganchem.2017.02.045
Abstract: Abstract Silver complexes of cyclic (alkyl)(amino)carbenes (CAACs), (RL)nAgX (n = 1, X = Cl, Br, I; n = 2, X = OTf; R = Me2, Et2, or adamantyl) are accessible in high yields by reacting free carbenes with silver salts. The smaller carbene ligand Me2L… read more here.
Keywords: complexes cyclic; silver complexes; amino carbenes; alkyl amino ... See more keywords
Hafnium(II) Complexes with Cyclic (Alkyl)(amino)carbene Ligation
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00688
Abstract: The formal hafnium(II) complexes with cyclic (alkyl)(amino)carbene (cAAC) ligation [(Me2-cAAC)2HfCl2] and [(Me2-cAAC)2Hf(CH2Ph)2] (Me2-cAAC = 1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidine-2-ylidene) have been synthesized and structurally characterized. read more here.
Keywords: amino carbene; complexes cyclic; hafnium complexes; alkyl amino ... See more keywords