Articles with "complexes dichlorosilylene" as a keyword



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Complexes of dichlorosilylene with allyl chloride and allyl bromide: matrix IR spectroscopy and quantum chemical studies

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Published in 2018 at "Russian Chemical Bulletin"

DOI: 10.1007/s11172-018-2089-4

Abstract: Formation of donor-acceptor complexes between dichlorosilylene, SiCl2, and allyl halides, AllHal(Hal= Cl, Br) was detected in Ar matrixes using matrix IR spectroscopy. In agreement with the predictions of the performed quantum chemical calculations, only broad… read more here.

Keywords: matrix spectroscopy; quantum chemical; allyl; complexes dichlorosilylene ... See more keywords