Exploring Covalency in f-Element Complexes: Dithiocarbamate Ligands Reveal Differences Between Heavy Actinides and Lanthanides.
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.4c04570
Abstract: Covalence in f-elements plays a pivotal role in distinguishing the fundamental properties of actinides and lanthanides. In this study, trivalent and tetravalent actinide (U-Fm) and lanthanide (Nd-Er) complexes with dithiocarbamate (S2CNH2-) ligands were systematically analyzed.… read more here.
Keywords: exploring covalency; complexes dithiocarbamate; actinides lanthanides; covalence heavy ... See more keywords
Zn(II) and Cd(II) complexes of dithiocarbamate ligands: synthesis, characterization, anticancer, and theoretical studies
Sign Up to like & getrecommendations! Published in 2024 at "Journal of Sulfur Chemistry"
DOI: 10.1080/17415993.2024.2384751
Abstract: ABSTRACT A potassium 4-(ethoxycarbonyl)phenyldithiocarbamate, (4-etphdtc), and 6-ethoxybenzothiazol)-dithiocarbamate, (6-etbedtc), ligands have been isolated and four metal dithiocarbamate complexes of the type [M(4-etphdtc)2] and [M(6-etbedtc)2] (M = Zn, Cd;) were synthesized and characterized by elemental analysis and spectroscopic techniques… read more here.
Keywords: anticancer theoretical; complexes dithiocarbamate; characterization anticancer; synthesis characterization ... See more keywords