Homodinuclear Lanthanide Complexes with the Divergent Heterotopic 4,4′-BipyridineN-Oxide (bipyMO) Ligand
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DOI: 10.1002/ejic.201800747
Abstract: The synthesis of dinuclear molecular complexes [Eu2(dbm)6(bipyMO)2], 1, [Tb2(dbm)6(bipyMO)2], 2, [Eu2(tta)6(bipyMO)2], 3 [Eu2(hfac)6(bipyMO)3], 4, [Tb2(hfac)6(bipyMO)3], 5 is here reported (bipyMO = 4,4’bipyridine-N-oxide, Hdbm = dibenzoylmethane, Htta = thenoyltrifluoroacetone, Hhfac=hexafluoroacetylacetone). The products were obtained in mild… read more here.
Keywords: divergent heterotopic; lanthanide complexes; bipymo; complexes divergent ... See more keywords
Cerium(III) yldiide complexes with divergent CO reactivity.
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DOI: 10.1039/d4cc04562a
Abstract: Synthesis of cerium yldiide complexes and their reactivity with CO is demonstrated. In the case of the sulphur-tethered yldiide, the ketenyl complex is formed with release of PPh3, while Ph3PCCO is formed along with a… read more here.
Keywords: yldiide complexes; complexes divergent; cerium iii; reactivity ... See more keywords