Synthesis and electrochemical investigations of the ortho-metalated complexes [Fe2(CO)6{к,μ-S,η2-(R)}] and their substitution reactions
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DOI: 10.1016/j.ica.2019.119377
Abstract: Abstract Modifications of the dithiolate linkers that connect the two iron atoms of the synthetic H-cluster mimics of [FeFe] hydrogenase play a significant role on tuning its physical and electrochemical properties. In this report, we… read more here.
Keywords: electrochemical investigations; ortho metalated; metalated complexes; synthesis electrochemical ... See more keywords
Synthesis, characterization and electrochemical properties of diiron azadithiolate complexes Fe2[(μ-SCH2)2NCH2CCH](CO)5L (L = CO or monophosphines)
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DOI: 10.1016/j.poly.2020.115007
Abstract: Abstract Diiron azadithiolate complexes are considered as important biomimetic models for the diiron subsite of [FeFe]-hydrogenases. Here, the diiron azadithiolate complex Fe2[(μ-SCH2)2NCH2CCH](CO)6 (1), produced by the condensation reaction of Fe2(μ-SCH2OH)2(CO)6 and NH2CH2CCH, is described. Meanwhile,… read more here.
Keywords: diiron azadithiolate; azadithiolate complexes; azadithiolate; complexes fe2 ... See more keywords
PNP-Chelated and -Bridged Diiron Dithiolate Complexes Fe2(μ-pdt)(CO)4{(Ph2P)2NR} Together with Related Monophosphine Complexes for the [2Fe]H Subsite of [FeFe]-Hydrogenases: Preparation, Structure, and Electrocatalysis
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DOI: 10.1021/acs.organomet.8b00030
Abstract: As the [2Fe]H subsite models of [FeFe]-hydrogenases, a series of PNP-chelated and -bridged diiron dithiolate complexes 1a–f and 2a–f together with the three related monophosphine complexes 3a–c were prepared by the selective substitutions of the… read more here.
Keywords: pnp; fe2 pdt; complexes fe2; pnp chelated ... See more keywords