Bis-Heteroleptic Cationic Iridium(III) Complexes Featuring Cyclometalating 2-Phenylbenzimidazole Ligands: A Combined Experimental and Theoretical Study.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02968
Abstract: In this report, we investigate a new family of cationic iridium(III) complexes featuring the cyclometalating ligand 2-phenylbenzimidazole and ancillary ligand 4,4'-dimethyl-2,2'-bipyridine. Our benchmark complex IrL12 (L1 = 2-phenylbenzimidazole) displays emission properties similar to those of… read more here.
Keywords: cationic iridium; iridium iii; iridium; iii complexes ... See more keywords
Luminescent Pt(II) complexes featuring imidazolylidene–pyridylidene and dianionic bipyrazolate: from fundamentals to OLED fabrications
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Materials Chemistry C"
DOI: 10.1039/c6tc05154e
Abstract: Pt(II) complexes bearing imidazolylidene–pyridylidene (impy) and dianionic biazolate chelates were synthesized, for which the end products depend on the alkyl substituents of the impy chelate. Treatment of Pt(DMSO)2Cl2 with dimethyl substituted imidazolium–pyridinium pro-ligand Me2impy(PF6)2, followed… read more here.
Keywords: pyridylidene; luminescent complexes; pf6; imidazolylidene pyridylidene ... See more keywords
Mononuclear Mn complexes featuring N,S-/N,N-donor and 1,3,5-triaza-7-phosphaadamantane ligands: synthesis and electrocatalytic properties
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DOI: 10.1039/d1nj02104d
Abstract: Two phosphaadamantane-substituted, new mononuclear Mn(I) carbonyl complexes, fac-[Mn(CO)3(κ2-S2NC7H4)(PTA)] 1 and fac-[Mn(CO)3(κ2-SN2C7H5)(PTA)] 2, were synthesized by the aerobic reaction of dinuclear {MnMn} complexes [Mn2(CO)6(µ-S2NC7H4)2] A and [Mn2(CO)6(µ-SN2C7H5)2] B with 1,3,5-triaza-7-phosphaadamantane (PTA) ligand in dichloromethane at room… read more here.
Keywords: triaza phosphaadamantane; featuring donor; mononuclear complexes; complexes featuring ... See more keywords