Bis-Heteroleptic Cationic Iridium(III) Complexes Featuring Cyclometalating 2-Phenylbenzimidazole Ligands: A Combined Experimental and Theoretical Study.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02968
Abstract: In this report, we investigate a new family of cationic iridium(III) complexes featuring the cyclometalating ligand 2-phenylbenzimidazole and ancillary ligand 4,4'-dimethyl-2,2'-bipyridine. Our benchmark complex IrL12 (L1 = 2-phenylbenzimidazole) displays emission properties similar to those of… read more here.
Keywords: cationic iridium; iridium iii; iridium; iii complexes ... See more keywords
Visible Light-Activatable Organoboron Complexes Featuring Salicylaldehyde Azine Ligands for Rapid Cationic Polymerization and Mechanism Studies.
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c00783
Abstract: Rapid polymerization controlled by visible light holds great potential for advancing 3D printing technologies. However, a significant challenge limiting the implementation of visible-light-activated polymerizations is its low efficiency compared to UV light driven processes. To… read more here.
Keywords: light activatable; visible light; cationic polymerization; polymerization ... See more keywords
Luminescent Pt(II) complexes featuring imidazolylidene–pyridylidene and dianionic bipyrazolate: from fundamentals to OLED fabrications
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Materials Chemistry C"
DOI: 10.1039/c6tc05154e
Abstract: Pt(II) complexes bearing imidazolylidene–pyridylidene (impy) and dianionic biazolate chelates were synthesized, for which the end products depend on the alkyl substituents of the impy chelate. Treatment of Pt(DMSO)2Cl2 with dimethyl substituted imidazolium–pyridinium pro-ligand Me2impy(PF6)2, followed… read more here.
Keywords: pyridylidene; luminescent complexes; pf6; imidazolylidene pyridylidene ... See more keywords
Mononuclear Mn complexes featuring N,S-/N,N-donor and 1,3,5-triaza-7-phosphaadamantane ligands: synthesis and electrocatalytic properties
Sign Up to like & getrecommendations! Published in 2021 at "New Journal of Chemistry"
DOI: 10.1039/d1nj02104d
Abstract: Two phosphaadamantane-substituted, new mononuclear Mn(I) carbonyl complexes, fac-[Mn(CO)3(κ2-S2NC7H4)(PTA)] 1 and fac-[Mn(CO)3(κ2-SN2C7H5)(PTA)] 2, were synthesized by the aerobic reaction of dinuclear {MnMn} complexes [Mn2(CO)6(µ-S2NC7H4)2] A and [Mn2(CO)6(µ-SN2C7H5)2] B with 1,3,5-triaza-7-phosphaadamantane (PTA) ligand in dichloromethane at room… read more here.
Keywords: triaza phosphaadamantane; featuring donor; mononuclear complexes; complexes featuring ... See more keywords
Dinuclear platinum(ii) complexes featuring rigidly linked Pt(NCN)X units: the effect of X = SCN− in favouring low-energy, excimer-like luminescence
Sign Up to like & getrecommendations! Published in 2024 at "New Journal of Chemistry"
DOI: 10.1039/d4nj03357d
Abstract: In tweezer-like dinuclear platinum(ii) complexes, the exchange of the chloride ligand for thiocyanate promotes interfacial interactions, leading to low-energy emission. read more here.
Keywords: platinum complexes; complexes featuring; low energy; dinuclear platinum ... See more keywords
Chiral Transition Metal Complexes Featuring Limonene-Derived Ligands: Roles in Catalysis and Biology
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DOI: 10.3390/inorganics13100336
Abstract: Chiral coordination compounds are of growing interest due to their structural diversity and wide applicability. Besides chirality, alcohol and especially oxime-functionalized limonene derivatives confer water solubility, stability, and the appropriate reactivity to enable their use… read more here.
Keywords: transition metal; chiral transition; biology; complexes featuring ... See more keywords
Triiron Complexes Featuring Azadiphosphine Related to the Active Site of [FeFe]-Hydrogenases: Their Redox Behavior and Protonation
Sign Up to like & getrecommendations! Published in 2024 at "Molecules"
DOI: 10.3390/molecules29143270
Abstract: The design of iron clusters featuring a bimetallic core and several protonation sites in the second coordination sphere of the metal centers is important for modeling the activity of polymetallic active sites such as the… read more here.
Keywords: triiron; fefe hydrogenases; triiron complexes; protonation ... See more keywords